Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides

José Gracia; Avelino Martı́n; Miguel Mena; M.Del C. Morales-Varela; Josep M. Poblet; Cristina Santamarı́a

doi:10.1002/anie.200390246

ScienceGate Book Chapters

JOURNAL ARTICLE

Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides

José Gracia Avelino Martı́n Miguel Mena M.Del C. Morales-Varela Josep M. Poblet Cristina Santamarı́a

Year: 2003 Journal: Angewandte Chemie International Edition Vol: 42 (8)Pages: 927-930 Publisher: Wiley

DOI: 10.1002/anie.200390246

Get Full-Text PDF Get Analytical Report

Abstract

Deprotonation of the complex [{Ti(η5-C5Me5)(μ-O)}3(μ3-CH)] with different alkali metal alkyl and amide reagents provides a method for the intercalation of alkali-metal ions into layered organometallic titanium oxides (see picture). The process and the structures were analyzed by DFT calculations.

Keywords:

Alkali metal Deprotonation Intercalation (chemistry) Amide Inorganic chemistry Chemistry Reagent Alkyl Metal Titanium Polymer chemistry Ion Organic chemistry

Metrics

Cited By

1.89

FWCI (Field Weighted Citation Impact)

Refs

0.82

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides

Abstract

Metrics

Citation History

Topics

Related Documents

Intercalation of Alkali Metal Cations into Layered Organotitanium Oxides

Alkali metal intercalation in layered oxides

Alkali metal intercalation into SnS2

Insertion study of alkali metal cations into layered vanadium oxide foam

Alkali Metal Intercalation-Deintercalation Reactions in 2D Oxides