JOURNAL ARTICLE

Aqua(2,2′-bipyridine-κ2 N,N′)bis(4-formylbenzoato-κ2 O,O′)cadmium(II) monohydrate

Zhao‐Peng DengShan GaoLi-Hua HuoHui Zhao

Year: 2007 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 63 (11)Pages: m2799-m2799   Publisher: International Union of Crystallography

Abstract

In the mononuclear title compound, [Cd(C 8 H 5 O 3 ) 2 (C 10 H 8 N 2 )(H 2 O)]·H 2 O, the Cd atom is O , O ′-chelated by two 4-formylbenzoate monoanions and N , N ′-chelated by 2,2′-bipyridine. It is also coordinated by a water molecule in a monocapped trigonal-prismatic geometry. The coordinated and solvent water molecules and O atoms of the monoanions engage in hydrogen bonding, resulting in a chain running along the b axis of the monoclinic unit cell.

Keywords:
Molecule Monoclinic crystal system Crystallography Chelation Hydrogen bond 2,2'-Bipyridine Chemistry Solvent Cadmium Bipyridine Atom (system on chip) Stereochemistry Inorganic chemistry Crystal structure Organic chemistry

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Citation History

Topics

Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Metal complexes synthesis and properties
Health Sciences →  Medicine →  Oncology
Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences →  Chemistry →  Inorganic Chemistry

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