JOURNAL ARTICLE
Spacer Cations Dictate Photoinduced Phase Segregation in 2D Mixed Halide Perovskites
Preethi Susan MathewJeffrey T. DuBoseJunsang ChoPrashant V. Kamat
Year: 2021 Journal: ACS Energy Letters Vol: 6 (7)Pages: 2499-2501 Publisher: American Chemical Society
Abstract
The spacer cation in two-dimensional (2D) Ruddlesden–Popper lead halide perovskites dictates photoinduced phase segregation. Halide ion segregation under steady-state irradiation of single-layer (n = 1) 2D perovskites is seen when butylammonium (BA) is used as the spacer cation, whereas it is essentially absent when BA is replaced with phenethylammonium (PEA).
Keywords:
Halide Phase (matter) Perovskite (structure) Ion Chemistry Irradiation Materials science Inorganic chemistry Crystallography Photochemistry Physics Organic chemistry
Metrics
65
Cited By
5.13
FWCI (Field Weighted Citation Impact)
26
Refs
0.97
Citation Normalized Percentile
Is in top 1%
Is in top 10%
Citation History
Topics
Perovskite Materials and Applications
Physical Sciences → Engineering → Electrical and Electronic Engineering
Conducting polymers and applications
Physical Sciences → Materials Science → Polymers and Plastics
Transition Metal Oxide Nanomaterials
Physical Sciences → Materials Science → Polymers and Plastics
Related Documents
JOURNAL ARTICLE
Spacer Cations Dictate Photoinduced Phase Segregation\nin 2D Mixed Halide Perovskites
PreethiS. Mathew (10974562)Jeffrey T. DuBose (8200692)Junsang Cho (3048825)Prashant V. Kamat (1271493)
Journal: OPAL (Open@LaTrobe) (La Trobe University) Year: 2021
JOURNAL ARTICLE
Suppressing photoinduced phase segregation in mixed halide perovskites
Journal: Journal of Semiconductors Year: 2022 Vol: 43 (2)Pages: 020201-020201
JOURNAL ARTICLE
Photoinduced Anion Segregation in Mixed Halide Perovskites
Michael C. BrennanAnthony RuthPrashant V. KamatMasaru Kuno
Journal: Trends in Chemistry Year: 2020 Vol: 2 (4)Pages: 282-301
JOURNAL ARTICLE
How Chloride Suppresses Photoinduced Phase Segregation in Mixed Halide Perovskites
Junsang Cho (3048825)Prashant V. Kamat (1271493)
Journal: OPAL (Open@LaTrobe) (La Trobe University) Year: 2020
JOURNAL ARTICLE
How Chloride Suppresses Photoinduced Phase Segregation in Mixed Halide Perovskites
Journal: Chemistry of Materials Year: 2020 Vol: 32 (14)Pages: 6206-6212