Heterodinuclear complexes featuring Zn(<scp>ii</scp>) and M = Al(<scp>iii</scp>), Ga(<scp>iii</scp>) or In(<scp>iii</scp>) for cyclohexene oxide and CO<sub>2</sub> copolymerisation

Arron C. Deacy; Christopher B. Durr; Charlotte K. Williams

doi:10.1039/c9dt02918d

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Heterodinuclear complexes featuring Zn(ii) and M = Al(iii), Ga(iii) or In(iii) for cyclohexene oxide and CO₂ copolymerisation

Arron C. Deacy Christopher B. Durr Charlotte K. Williams

Year: 2019 Journal: Dalton Transactions Vol: 49 (1)Pages: 223-231 Publisher: Royal Society of Chemistry

DOI: 10.1039/c9dt02918d

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Abstract

A series of heterodinuclear zinc(ii)-Group 13 catalysts are synthesised by a sequential metalation procedure. They are active catalysts for the ring opening copolymerisation of cyclohexene oxide and CO₂.

Keywords:

Chemistry Oxide Stereochemistry Medicinal chemistry Polymer chemistry Organic chemistry

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Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

CO2 Reduction Techniques and Catalysts

Physical Sciences → Energy → Renewable Energy, Sustainability and the Environment

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Heterodinuclear complexes featuring Zn(ii) and M = Al(iii), Ga(iii) or In(iii) for cyclohexene oxide and CO₂ copolymerisation

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