Excited-state effects on magnetic properties of U(<scp>iii</scp>) and U(<scp>iv</scp>) pyrazolylborate complexes

Robert F. Higgins; Caleb J. Tatebe; Suzanne C. Bart; Matthew P. Shores

doi:10.1039/c9cc04800f

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Excited-state effects on magnetic properties of U(iii) and U(iv) pyrazolylborate complexes

Robert F. Higgins Caleb J. Tatebe Suzanne C. Bart Matthew P. Shores

Year: 2019 Journal: Chemical Communications Vol: 55 (71)Pages: 10611-10614 Publisher: Royal Society of Chemistry

DOI: 10.1039/c9cc04800f

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Abstract

For a family of uranium pyrazolylborate complexes, we observe correlations between excited-state mixing and slow relaxation of magnetization for U(iii) complexes, and U⋯B distances in U(iv) complexes.

Keywords:

Excited state Chemistry Physics Atomic physics

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Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Electron Spin Resonance Studies

Life Sciences → Biochemistry, Genetics and Molecular Biology → Biophysics

Excited-state effects on magnetic properties of U(iii) and U(iv) pyrazolylborate complexes

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