Homoleptic U(<scp>iii</scp>) and U(<scp>iv</scp>) amidate complexes

Mark D. Straub; Stephan Hohloch; Stefan G. Minasian; John Arnold

doi:10.1039/c7dt04813k

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Homoleptic U(iii) and U(iv) amidate complexes

Mark D. Straub Stephan Hohloch Stefan G. Minasian John Arnold

Year: 2018 Journal: Dalton Transactions Vol: 47 (6)Pages: 1772-1776 Publisher: Royal Society of Chemistry

DOI: 10.1039/c7dt04813k

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Abstract

Homoleptic U(iv) and U(iii) amidate complexes have been isolated and characterized; these species undergo an unusual and reversible change in coordination number upon reduction/oxidation.

Keywords:

Homoleptic Chemistry Coordination number Stereochemistry Ion Metal Organic chemistry

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Radioactive element chemistry and processing

Physical Sciences → Chemistry → Inorganic Chemistry

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Radiopharmaceutical Chemistry and Applications

Health Sciences → Medicine → Radiology, Nuclear Medicine and Imaging

Homoleptic U(iii) and U(iv) amidate complexes

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