JOURNAL ARTICLE
Synthesis of the Isolable Biradicals •(CH3B)11C−C⋮C−C(BCH3)11• and trans-•(CH3B)11C−CHCH−C(BCH3)11•
Ludvig ErikssonKamesh VyakaranamJiřı́ Ludvı́kJosef Michl
Year: 2007 Journal: The Journal of Organic Chemistry Vol: 72 (7)Pages: 2351-2356 Publisher: American Chemical Society
Abstract
A synthesis of ethene and ethyne derivatives carrying the anionic -C(BCH3)11- substituent on one or both carbon atoms is described. Two-electron oxidation of the dianions yielded the stable and isolable electroneutral title biradicals.
Keywords:
Chemistry Substituent Medicinal chemistry Carbyne Stereochemistry Organic chemistry Carbene Catalysis
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36
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4.78
FWCI (Field Weighted Citation Impact)
10
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0.95
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Citation History
Topics
Crystallography and molecular interactions
Physical Sciences → Chemistry → Physical and Theoretical Chemistry
Organoboron and organosilicon chemistry
Physical Sciences → Chemistry → Organic Chemistry
Boron Compounds in Chemistry
Health Sciences → Medicine → Radiology, Nuclear Medicine and Imaging
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