JOURNAL ARTICLE

KF‐Montmorillonite‐catalyzed Michael Addition Reaction of Malononitrile to α,β‐Unsaturated Ketones

Daqing ShiNan WuQiya Zhuang

Year: 2009 Journal:   Chinese Journal of Chemistry Vol: 27 (1)Pages: 169-173   Publisher: Wiley

Abstract

Abstract The Michael addition reaction of α , β ‐unsaturated ketones with malononitrile catalyzed by KF‐montmorillonite was investigated. It was interesting to note that at different reaction temperatures the addition and cycloaddition reaction products were obtained. This method has the advantages of good yields, mild reaction conditions, easy work‐up and inexpensive reagents over the existing procedures.

Keywords:
Malononitrile Chemistry Reagent Montmorillonite Michael reaction Catalysis Cycloaddition Reaction conditions Organic chemistry Addition reaction

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Topics

Multicomponent Synthesis of Heterocycles
Physical Sciences →  Chemistry →  Organic Chemistry
Chemical Synthesis and Analysis
Life Sciences →  Biochemistry, Genetics and Molecular Biology →  Molecular Biology
Chemical Synthesis and Reactions
Physical Sciences →  Chemistry →  Organic Chemistry
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