JOURNAL ARTICLE

Michael Addition Reaction of Malononitrile andα,β-Unsaturated Ketones Catalyzed by Amine Functionalized MCM-41

Changchun WangShaolei XieZhengfeng XieYonghai Hui

Year: 2013 Journal:   Chinese Journal of Organic Chemistry Vol: 33 (11)Pages: 2391-2391   Publisher: Science Press

Abstract

Michael addition reaction of α,β-unsaturated ketones and malononitrile that catalyzed by amine functionalized MCM-41 in methanol afforded a series of cyano derivatives with high yield (up to 99%).The products were afforded at room temperature.Moreover, the catalyst was also found to easiness to handle up, friendly environment, and excellent recyclability.

Keywords:
Malononitrile Chemistry Michael reaction Amine gas treating Catalysis Yield (engineering) Methanol Organic chemistry Materials science

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Topics

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Physical Sciences →  Chemistry →  Organic Chemistry
Chemical Synthesis and Reactions
Physical Sciences →  Chemistry →  Organic Chemistry
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Physical Sciences →  Chemistry →  Organic Chemistry
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