JOURNAL ARTICLE
X-ray radiation-induced amorphization of metal–organic frameworks
Remo N. WidmerGiulio I. LamprontiNicola CasatiStefan FarsangThomas D. BennettSimon A. T. Redfern
Year: 2019 Journal: Physical Chemistry Chemical Physics Vol: 21 (23)Pages: 12389-12395 Publisher: Royal Society of Chemistry
Abstract
Accumulation of radiation damage from synchrotron X-rays leads to complete amorphization of the initially crystalline metal–organic frameworks ZIF-4, ZIF-62, and ZIF-zni. The mechanism of this transformation is studied as a function of time and temperature and is shown to be non-isokinetic.
Keywords:
Synchrotron radiation Nucleation Materials science Synchrotron Chemical physics Phase (matter) X-ray Metal-organic framework Thermal stability Thermodynamics Chemistry Physical chemistry Optics Physics Organic chemistry
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48
Cited By
2.42
FWCI (Field Weighted Citation Impact)
41
Refs
0.87
Citation Normalized Percentile
Is in top 1%
Is in top 10%
Citation History
Topics
Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences → Chemistry → Inorganic Chemistry
X-ray Diffraction in Crystallography
Physical Sciences → Materials Science → Materials Chemistry
Magnetism in coordination complexes
Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials
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