JOURNAL ARTICLE
Metal‐Free, Organocatalytic Asymmetric Transfer Hydrogenation of α,β‐Unsaturated Aldehydes
Jung Woon YangMaria T. Hechavarria FonsecaNicola VignolaBenjamin List
Year: 2004 Journal: Angewandte Chemie Vol: 117 (1)Pages: 110-112 Publisher: Wiley
Abstract
Selektive Reduktion ohne Metall: Ein Imidazolidinonsalz katalysiert effektiv die hoch enantioselektive biomimetische Transferhydrierung α,β-ungesättigter Aldehyde zu den gesättigten Analoga, bei der ein synthetischer Dihydropyridin-Cofaktor verwendet wird (siehe Schema). Dabei entsteht, unabhängig von der Konfiguration des Ausgangs-Enals, nur ein Enantiomer.
Keywords:
Chemistry Aldehyde Transfer hydrogenation Enantiomer Organocatalysis Enantioselective synthesis Stereochemistry Organic chemistry Catalysis
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27
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0.98
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Citation History
Topics
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
Chemical Synthesis and Analysis
Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology
Asymmetric Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
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