JOURNAL ARTICLE

Aquadichloro(η5-pentamethylcyclopentadienyl)iridium(III)

Li MaWenjie ZhaoKui Lü

Year: 2006 Journal:   Acta Crystallographica Section E Structure Reports Online Vol: 62 (10)Pages: m2524-m2525   Publisher: International Union of Crystallography

Abstract

Each IrIII ion in the title compound, [Ir(C10H15)Cl2(H2O)], is six-coordinated by two chloride ions, one water mol­ecule and a penta­methyl­cyclo­penta­dienyl (Cp*) ligand in a three-legged piano-stool geometry, assuming that the Cp* ligand functions as a tridentate ligand. There is hydrogen bonding between the water H atoms and the Cl atoms of adjacent mol­ecules.

Keywords:
Iridium Ligand (biochemistry) Chemistry Ion Chloride Hydrogen bond Crystallography Hydrogen Medicinal chemistry Molecule Organic chemistry Catalysis Receptor

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Topics

Lanthanide and Transition Metal Complexes
Physical Sciences →  Materials Science →  Materials Chemistry
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials
Supramolecular Chemistry and Complexes
Physical Sciences →  Chemistry →  Organic Chemistry

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