Unprecedented Li+ Exchange in an Anionic Metal–Organic Framework: Significantly Enhanced Gas Uptake Capacity
Bo LiuRui ZhangChun‐Yang PanHai‐Long Jiang
Abstract
We herein report the first example of Li+ exchanged with both the guest H2N(Me)2+ cations located in the channels and the coordinated metal ions from an anionic metal-organic framework (MOF), leading to significant enhancement of the pore volume and gas sorption abilities of the exchanged MOF. Furthermore, both MOFs before and after Li+ exchange show good selective adsorption for CO2 over CH4.
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