JOURNAL ARTICLE
Room-Temperature Activation of Hydrogen by Semi-immobilized Frustrated Lewis Pairs in Microporous Polymer Networks
Matthias TrunkJohannes F. TeichertArne Thomas
Year: 2017 Journal: Journal of the American Chemical Society Vol: 139 (10)Pages: 3615-3618 Publisher: American Chemical Society
Abstract
Porous polymer networks based on sterically encumbered triphenylphosphine motifs, mimicking the basic sites employed in frustrated Lewis pair (FLP) chemistry, were synthesized via Yamamoto polymerization and their interactions with the strong Lewis acid B(C6F5)3 probed. The combinations yield semi-immobilized FLPs, which are able to cleave dihydrogen heterolytically at ambient temperature and low hydrogen pressure.
Keywords:
Chemistry Frustrated Lewis pair Microporous material Lewis acids and bases Steric effects Polymer Polymerization Cleave Polymer chemistry Hydrogen Yield (engineering) Chemical engineering Organic chemistry Catalysis Enzyme Thermodynamics
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106
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5.22
FWCI (Field Weighted Citation Impact)
25
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0.96
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Citation History
Topics
Organoboron and organosilicon chemistry
Physical Sciences → Chemistry → Organic Chemistry
Covalent Organic Framework Applications
Physical Sciences → Materials Science → Materials Chemistry
Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences → Chemistry → Inorganic Chemistry
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