Synthesis of Polypyrrole/Poly(vinyl alcohol) Conductive Composite Foam by Vapor Phase Polymerization.

Feifeng He; Mitsuru Omoto; Toshihiro Yamamoto; Hideo Kise

doi:10.1295/koron.50.665

ScienceGate Book Chapters

JOURNAL ARTICLE

Synthesis of Polypyrrole/Poly(vinyl alcohol) Conductive Composite Foam by Vapor Phase Polymerization.

Feifeng He Mitsuru Omoto Toshihiro Yamamoto Hideo Kise

Year: 1993 Journal: KOBUNSHI RONBUNSHU Vol: 50 (9)Pages: 665-669 Publisher: Society of Polymer Science

DOI: 10.1295/koron.50.665

Get Full-Text PDF Get Analytical Report

Abstract

酸化剤として三価の鉄塩を含浸させた発泡ポリビニルアルコール (PVA) にピロール蒸気を接触させる気相重合法により, 導電性のポリピロール/PVA複合フォームを合成した. ピロールの重合時間とポリピロール複合量および複合フォームの導電率との関係を調べた. 酸化剤として塩化鉄または過塩素酸鉄を用いた場合には, 硫酸鉄や硝酸鉄の場合に比較して導電率の高い複合フォームが得られたが, 過塩素酸鉄の場合には, PVAの酸化が原因と思われるフォームの収縮硬化が起こった. 塩化鉄の場合, 0～20℃の範囲で, 重合温度の低下によりピロールの重合量は減少したが, 導電率は増加し, 最高O. 1 Scm-1に達した. 複合フォームの導電率は水分の吸収量により変化した. またSEMにより観測される表面構造は, 酸化剤の種類によりかなり変化した.

Keywords:

Polypyrrole Vinyl alcohol Materials science Polymerization Composite number Electrical conductor Polymer chemistry Composite material Vapor phase Chemical engineering Polymer

Metrics

Cited By

1.76

FWCI (Field Weighted Citation Impact)

Refs

0.84

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Conducting polymers and applications

Physical Sciences → Materials Science → Polymers and Plastics

Supercapacitor Materials and Fabrication

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Advanced Sensor and Energy Harvesting Materials

Physical Sciences → Engineering → Biomedical Engineering

Synthesis of Polypyrrole/Poly(vinyl alcohol) Conductive Composite Foam by Vapor Phase Polymerization.

Abstract

Metrics

Citation History

Topics

Related Documents

Preparation of Electrically Conductive Composite Foam of Polypyrrole/Polyurethane by Vapor-phase Polymerization.

Preparation of polypyrrole–polyurethane composite foam by vapor phase oxidative polymerization

Conductive polypyrrole composite films by chemical vapor polymerization

Preparation and Properties of Poly（vinyl alcohol）/polypyrrole Composite Conductive Hydrogel Strain Sensor

Effects of Polymerization Temperature and Oxidants on the Synthesis of Polypyrrole/Polyurethane Conductive Composite Foams by Vapor Phase Polymerization.