Enantioselective polymerization of γ‐benzyl‐<scp>DL</scp>‐glutamate <i>N</i>‐carboxy anhydride in the presence of poly(γ‐benzyl‐<scp>L</scp>‐glutamate)

Nobuki Oguni; Hiroaki Kuboyama; Akira Nakamura

doi:10.1002/pol.1983.170210601

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Enantioselective polymerization of γ‐benzyl‐DL‐glutamate N‐carboxy anhydride in the presence of poly(γ‐benzyl‐L‐glutamate)

Nobuki Oguni Hiroaki Kuboyama Akira Nakamura

Year: 1983 Journal: Journal of Polymer Science Polymer Chemistry Edition Vol: 21 (6)Pages: 1559-1565 Publisher: Wiley

DOI: 10.1002/pol.1983.170210601

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Abstract

Abstract The polymerization of γ‐benzyl‐ DL ‐glutamate NCA in the presence of poly(γ‐benzyl‐ L ‐glutamate) was investigated. At the initial stage the D ‐enantiomer was preferentially polymerized (ca. 35% ee) by using triethylamine as an initiator. Enantioselectivity was independent of the molecular weight of preformed poly(γ‐benzyl‐ DL ‐glutamate).

Keywords:

Triethylamine Polymerization Glutamate receptor Chemistry Enantiomer Polymer chemistry Organic chemistry Biochemistry Polymer Receptor

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Biopolymer Synthesis and Applications

Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology

Chemical Synthesis and Analysis

Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology

Advanced Polymer Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Enantioselective polymerization of γ‐benzyl‐DL‐glutamate N‐carboxy anhydride in the presence of poly(γ‐benzyl‐L‐glutamate)

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