[(Cp**CoH)2‐μ‐{η2:η2‐cis‐μ‐[(C2H5)2Al–CH = CH–Al(C2H5)2]}] and [{Cp*(η2‐C2H4)CoAl(C2H5)}2]: Synthesis and Structure of Unusual Co–Al Cluster Compounds

Jörg J. Schneider; Carl Krüger; M. Chester Nolte; Ingo Abraham; Teja S. Ertel; H. Bertagnolli

doi:10.1002/anie.199424351

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[(Cp^**CoH)₂‐μ‐{η²:η²‐cis‐μ‐[(C₂H₅)₂Al–CH = CH–Al(C₂H₅)₂]}] and [{Cp^*(η²‐C₂H₄)CoAl(C₂H₅)}₂]: Synthesis and Structure of Unusual Co–Al Cluster Compounds

Jörg J. Schneider Carl Krüger M. Chester Nolte Ingo Abraham Teja S. Ertel H. Bertagnolli

Year: 1995 Journal: Angewandte Chemie International Edition in English Vol: 33 (23-24)Pages: 2435-2437

DOI: 10.1002/anie.199424351

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Abstract

How many metal atoms can coordinate to a CC unit? The answer for Co–Al clusters 1 (R = Me) and 2 (R = Et), the first η-η2:η2-bridged dialumin-ioethene clusters, is “four”. The complexes are formed in about 30% yield on treatment of [Cp+(η2-ethene)2Co] (Cp+ = C5Me5, C5Me4Et) with AlEt2H.

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Yield (engineering) Crystallography Physics Metal Chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

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[(Cp^**CoH)₂‐μ‐{η²:η²‐cis‐μ‐[(C₂H₅)₂Al–CH = CH–Al(C₂H₅)₂]}] and [{Cp^*(η²‐C₂H₄)CoAl(C₂H₅)}₂]: Synthesis and Structure of Unusual Co–Al Cluster Compounds

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