[(Cp**CoH)22‐μ‐{η2:η2‐cis‐μ‐[(C2H5)2AI‐CHCHAI(C2H5)2]}] und [{Cp*(η2‐C2H4)‐CoAI(C2H5)}2]: Synthese und Struktur ungewöhnlicher Co‐AI‐Clusterverbindungen

Jörg J. Schneider; Carl Krüger; Matthias Nolte; Ingo Abraham; Teja S. Ertel; H. Bertagnolli

doi:10.1002/ange.19941062319

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[(Cp**CoH)₂₂‐μ‐{η²:η²‐cis‐μ‐[(C₂H₅)₂AI‐CHCHAI(C₂H₅)₂]}] und [{Cp^*(η²‐C₂H₄)‐CoAI(C₂H₅)}₂]: Synthese und Struktur ungewöhnlicher Co‐AI‐Clusterverbindungen

Jörg J. Schneider Carl Krüger Matthias Nolte Ingo Abraham Teja S. Ertel H. Bertagnolli

Year: 1994 Journal: Angewandte Chemie Vol: 106 (23-24)Pages: 2537-2540 Publisher: Wiley

DOI: 10.1002/ange.19941062319

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Abstract

Wie viele Metallatome können an eine CC‐Einheit koordiniert werden? Vier lautet die Antwort für die Co‐Al‐Cluster 1 (RMe) und 2 (R=Et), die ersten μ‐η 3 :η 2 ‐verbrückten Dialuminioethen‐Cluster. Die roten bzw. braunroten Komplexe entstehen bei der Umsetzung von [Cp+(η 2 ‐ethen) 2 Co](Cp+ = C 5 Me 5 , C 5 Me 4 Et) mit AlEt 2 H in ca. 30% Ausbeute. magnified image

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Cluster (spacecraft) Physics Crystallography X-ray crystallography Chemistry Stereochemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

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[(Cp**CoH)₂₂‐μ‐{η²:η²‐cis‐μ‐[(C₂H₅)₂AI‐CHCHAI(C₂H₅)₂]}] und [{Cp^*(η²‐C₂H₄)‐CoAI(C₂H₅)}₂]: Synthese und Struktur ungewöhnlicher Co‐AI‐Clusterverbindungen

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[(Cp^**CoH)₂‐μ‐{η²:η²‐cis‐μ‐[(C₂H₅)₂Al–CH = CH–Al(C₂H₅)₂]}] and [{Cp^*(η²‐C₂H₄)CoAl(C₂H₅)}₂]: Synthesis and Structure of Unusual Co–Al Cluster Compounds

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[(Cp**CoH)2‐μ‐{η2:η2‐cis‐μ‐[(C2H5)2Al–CH = CH–Al(C2H5)2]}] and [{Cp*(η2‐C2H4)CoAl(C2H5)}2]: Synthesis and Structure of Unusual Co–Al Cluster Compounds

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[(Cp^**CoH)₂‐μ‐{η²:η²‐cis‐μ‐[(C₂H₅)₂Al–CH = CH–Al(C₂H₅)₂]}] and [{Cp^*(η²‐C₂H₄)CoAl(C₂H₅)}₂]: Synthesis and Structure of Unusual Co–Al Cluster Compounds

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