Agostic‐type Gold Ligand and Incipient μ3‐PPh2 Coordination in the Au2Pt2P6 “Hammock” Skeleton of the Cluster [Au2Pt2(μ‐PPh2)2(PPh3)4][PF6]2

R. Bender; Pierre Braunstein; Alain Dedieu; Yves Dusausoy

doi:10.1002/anie.198909231

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Agostic‐type Gold Ligand and Incipient μ₃‐PPh₂ Coordination in the Au₂Pt₂P₆ “Hammock” Skeleton of the Cluster [Au₂Pt₂(μ‐PPh₂)₂(PPh₃)₄][PF₆]₂

R. Bender Pierre Braunstein Alain Dedieu Yves Dusausoy

Year: 1989 Journal: Angewandte Chemie International Edition in English Vol: 28 (7)Pages: 923-925

DOI: 10.1002/anie.198909231

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Abstract

Not only bonds between Au and Pt but also between Au and the Ph2P bridge ligands characterize the structure of 2, which is formed in ca. 80 % yield upon reaction of two equivalents of [Au(PPh3)]⊕ with 1 in CH2Cl2.

Keywords:

Agostic interaction Crystallography Yield (engineering) Ligand (biochemistry) Chemistry Bridge (graph theory) Skeleton (computer programming) Materials science Metallurgy Metal

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Organometallic Complex Synthesis and Catalysis

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Agostic‐type Gold Ligand and Incipient μ₃‐PPh₂ Coordination in the Au₂Pt₂P₆ “Hammock” Skeleton of the Cluster [Au₂Pt₂(μ‐PPh₂)₂(PPh₃)₄][PF₆]₂

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Agostic‐type Gold Ligand and Incipient μ3‐PPh2 Coordination in the Au2Pt2P6 “Hammock” Skeleton of the Cluster [Au2Pt2(μ‐PPh2)2(PPh3)4][PF6]2

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Eine Art agostische Gold‐Ligand‐ und eine μ3‐PPh2‐Koordination im „Hängematten”; Au2Pt2P6‐Skelett des Clusters [Au2Pt2(μ‐PPh2)2(PPh3)4](PF6)2

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