JOURNAL ARTICLE
Reactions of trinuclear platinum clusters with electrophiles: ionisation isomerism with [Pt3(μ2-I)(μ-PPh2)2(PPh3)3]I and [Pt3(μ-PPh2)2I2(PPh3)3]. Structures of [Pt3(μ2-Cl)(μ-PPh2)2(PPh3)3]PF6, [Pt3(μ-PPh2)2I2(PPh3)3] and of the Pt–Ag cluster [Pt3{μ3-AgBF4}(μ2-I)(μ-PPh2)2(PPh3)3]BF4
Christine ArchambaultR. BenderPierre BraunsteinYves DusausoyR. Welter
Year: 2014 Journal: Dalton Transactions Vol: 43 (23)Pages: 8609-8619 Publisher: Royal Society of Chemistry
Abstract
Reactions of the mixed-valence cluster [Pt3(μ-PPh2)3Ph(PPh3)2] with various electrophiles have been investigated.
Keywords:
Adduct Chemistry Cationic polymerization Crystallography Cluster (spacecraft) Crystal structure Electrophile Recrystallization (geology) Toluene Stereochemistry Medicinal chemistry Catalysis Polymer chemistry Organic chemistry
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64
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0.68
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Citation History
Topics
Organometallic Complex Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
Magnetism in coordination complexes
Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials
Metal complexes synthesis and properties
Health Sciences → Medicine → Oncology
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