Bis(μ2-quinoline-2-carboxylato)-κ3N,O1:O1;κ3O1:N,O1-bis[(acetato-κO)(ethanol-κO)lead(II)]

Ezzatollah Najafi; Mostafa M. Amini; Seik Weng Ng

doi:10.1107/s1600536811002509

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Bis(μ₂-quinoline-2-carboxylato)-κ³N,O¹:O¹;κ³O¹:N,O¹-bis[(acetato-κO)(ethanol-κO)lead(II)]

Ezzatollah Najafi Mostafa M. Amini Seik Weng Ng

Year: 2011 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 67 (2)Pages: m264-m264 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536811002509

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Abstract

In the centrosymmetric dinuclear title compound, [Pb(2)(C(10)H(6)NO(2))(2)(CH(3)COO)(2)(C(2)H(5)OH)(2)], one O atom of the carboxyl-ate group of the quinoline-2-carboxyl-ate anion connects the two Pb(II) atoms. The Pb(II) atom is surrounded by four O atoms and one N atom in a Ψ-octa-hedral PbO(4)NE geometry (E is the electron lone pair). Two longer Pb⋯O inter-actions distort the geometry towards a Ψ-square-anti-prism. Inter-molecular O-H⋯O hydrogen bonds link the mol-ecules.

Keywords:

Chemistry Quinoline Lone pair Crystallography Atom (system on chip) Hydrogen bond Ion Bioinformatics Stereochemistry Molecule

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Crystallography and molecular interactions

Physical Sciences → Chemistry → Physical and Theoretical Chemistry

Lanthanide and Transition Metal Complexes

Physical Sciences → Materials Science → Materials Chemistry

Bis(μ₂-quinoline-2-carboxylato)-κ³N,O¹:O¹;κ³O¹:N,O¹-bis[(acetato-κO)(ethanol-κO)lead(II)]

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