Surface Activation of Electrocatalysis at Oxide Electrodes. Concerted Electron−Proton Transfer

Christopher J. Gagliardi; Jonah W. Jurss; H. Holden Thorp; Thomas J. Meyer

doi:10.1021/ic102524f

ScienceGate Book Chapters

JOURNAL ARTICLE

Surface Activation of Electrocatalysis at Oxide Electrodes. Concerted Electron−Proton Transfer

Christopher J. Gagliardi Jonah W. Jurss H. Holden Thorp Thomas J. Meyer

Year: 2011 Journal: Inorganic Chemistry Vol: 50 (6)Pages: 2076-2078 Publisher: American Chemical Society

DOI: 10.1021/ic102524f

Get Full-Text PDF Get Analytical Report

Abstract

Dramatic rate enhancements are observed for the oxidation of phenols, including tyrosine, at indium-tin oxide electrodes modified by the addition of the electron-transfer relays [M(II)(bpy)(2)(4,4'-(HO)(2)P(O)CH(2))(2)bpy)](2+) (M = Ru, Os) with clear evidence for the importance of proton-coupled electron transfer and concerted electron-proton transfer.

Keywords:

Chemistry Electron transfer Proton-coupled electron transfer Electrocatalyst Proton Electrode Oxide Photochemistry Inorganic chemistry Electrochemistry Physical chemistry Organic chemistry

Metrics

Cited By

2.04

FWCI (Field Weighted Citation Impact)

Refs

0.84

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Electrochemical Analysis and Applications

Physical Sciences → Chemistry → Electrochemistry

Photochemistry and Electron Transfer Studies

Physical Sciences → Chemistry → Physical and Theoretical Chemistry

Electrocatalysts for Energy Conversion

Physical Sciences → Energy → Renewable Energy, Sustainability and the Environment

Surface Activation of Electrocatalysis at Oxide Electrodes. Concerted Electron−Proton Transfer

Abstract

Metrics

Citation History

Topics

Related Documents

Surface Activation of Electrocatalysis at Oxide Electrodes. Concerted Electron−Proton Transfer

Concerted Proton-Electron Transfer Minimizes Substituent Effects on Adsorbed Phthalocyanine Electrocatalysis

Concerted Proton-Electron Transfer

Improved nitrate-to-ammonia electrocatalysis through concerted proton-coupled electron transfer

Concerted Proton-Electron Transfer Reactions