JOURNAL ARTICLE

Notizen: Darstellung, IR-Spektrum und Kristalldaten von [ReNCl3 · POCl3]4 · 2POCl3/Preparation, IR Spectrum and Crystallographic Data of [ReNCL · POCl3]4 · 2 POCl3

W LieseKurt DehnickeI. WalkerJoachim Strähle

Year: 1980 Journal:   Zeitschrift für Naturforschung B Vol: 35 (6)Pages: 776-777   Publisher: De Gruyter

Abstract

Abstract The title compound is prepared by treating ReNCL with excess POCl 3 . The complex is isotypic with the corresponding tungsten complex [WNCl 3 · POCl 3 ] 4 · 2 POCl 3 . The structure consists of Re 4 N 4 eight-membered rings with alternating Re ≡ N-Re bonds. The IR spectrum was recorded and assigned.

Keywords:
Materials science Crystallography Chemistry

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Topics

Inorganic Chemistry and Materials
Physical Sciences →  Chemistry →  Inorganic Chemistry
Synthesis and characterization of novel inorganic/organometallic compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Organometallic Complex Synthesis and Catalysis
Physical Sciences →  Chemistry →  Organic Chemistry

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