Experimental evidence is given to show that the magnetocrystalline anistropy of silicondoped yttrium iron garnet, nominal composition ${\mathrm{Y}}_{3}$${\mathrm{Fe}}_{4.9}$${\mathrm{Si}}_{0.1}$${\mathrm{O}}_{12}$, can be changed by more than 100 Oe at 20\ifmmode^\circ\else\textdegree\fi{}K through irradiation with near-infrared photons. The change is interpreted as due to the redistribution of electrons between iron ions, that is valence exchange.
R. F. PearsonA. D. AnnisP. Kompfner
Chen S. TsaiC. L. WangYunfei Pu
R W TealeD. W. TempleD I Weatherley
Toshihiro ShintakuTakehiko UnoM. Kobayashi