Darstellung und Struktur eines zweikernigen Vanadium(V)-Komplexes mit den terminal gebundenen Stickstoffliganden N^tC₄H₉, NH^tC₄H₉ und NH₂ ^tC₄H₉: [ VCl(μ-Cl)(N^tC₄H₉)(NH^tC₄H₉) (NH₂ ^tC₄H₉) ]₂ / Synthesis and Molecular Structure of a Binuclear Vanadium(V) Complex Containing the Terminal Nitrogen Ligands N^tC₄H₉, NH^tC₄H₉, NH₂ ^tC₄H₉: [VCl(μ-Cl)(N^tC₄H₉)(NH^tC₄H₉)(NH₂ ^tC₄H₉)]₂

Abstract

t C 4 H 9 N = VCl 2 (NH t C 4 H 9 ) and the tert-butylamine complex [ t C 4 H 9 N=VCl 2 (NH t C 4 H 9 )(NH 2 t C 4 H 9 )] have been prepared by reaction of t C 4 H 9 N=VCl 3 with NH 2 t C 4 H 9 . 1 H and 51 V NMR data of these compounds are reported. The complex was investigated by X-ray diffraction analysis; the structure has been found to be a binuclear vanadium complex bridged by two Cl-atoms with a distorted octahedral arrangement of the ligands.