Strukturen 2‐(Me2NCH2)C6H4‐substituierter Oligosilane

Johannes Belzner; Nicola Detomi; Heiko Ihmels; Matthias Noltemeyer

doi:10.1002/ange.19941061822

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Strukturen 2‐(Me₂NCH₂)C₆H₄‐substituierter Oligosilane

Johannes Belzner Nicola Detomi Heiko Ihmels Matthias Noltemeyer

Year: 1994 Journal: Angewandte Chemie Vol: 106 (18)Pages: 1949-1950 Publisher: Wiley

DOI: 10.1002/ange.19941061822

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Abstract

Nahezu unverzerrt ist der Dreiring des Cyclotrisilans 1 . Dies liegt in dem sterisch wenig anspruchsvollen 2‐(Dimethylaminomethyl)phenyl‐Liganden begründet, der auch die Ursache für die unerwartete synperiplanare Konformation des Disilens 2 ist. magnified image

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Chemistry Stereochemistry Crystallography

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Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Strukturen 2‐(Me₂NCH₂)C₆H₄‐substituierter Oligosilane

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Strukturen 2‐(Me2NCH2)C6H4‐substituierter Oligosilane

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ChemInform Abstract: Electronic and Electrochemical Properties of Platinum(II) and Platinum‐mercurycarboxylato Complexes Containing 2‐Me2NCH2C5H4‐, 2,6‐(Me2NCH2)2C6H3‐ and 2‐Me2NC6H4CH, Ligands.

Isomers of a Dibismuthane, R2Bi−BiR2 [R = 2,6-(Me2NCH2)2C6H3], and Unusual Reactions with Oxygen: Formation of [R2Bi]2(O2) and R‘R‘ ‘Bi [R‘ = 2-(Me2NCH2)-6-{Me2N(O)CH2}C6H3; R‘ ‘ = 2-(Me2NCH2)-6-{O(O)C}C6H3]

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