Structures of 2‐(Me2NCH2)C6H4‐Substituted Oligosilanes

Johannes Belzner; Nicola Detomi; Heiko Ihmels; Matthias Noltemeyer

doi:10.1002/anie.199418541

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Structures of 2‐(Me₂NCH₂)C₆H₄‐Substituted Oligosilanes

Johannes Belzner Nicola Detomi Heiko Ihmels Matthias Noltemeyer

Year: 1994 Journal: Angewandte Chemie International Edition in English Vol: 33 (18)Pages: 1854-1855

DOI: 10.1002/anie.199418541

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Abstract

The three-membered ring of cyclotrisilane 1 is almost undistorted. This is a result of the only moderate steric bulk of the 2-(dimethylaminomethyl)phenyl ligand, which also dictates the unexpected synperiplanar conformation of disilene 2.

Keywords:

Steric effects Ring (chemistry) Ligand (biochemistry) Stereochemistry Chemistry Crystallography Organic chemistry

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Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Structures of 2‐(Me₂NCH₂)C₆H₄‐Substituted Oligosilanes

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Strukturen 2‐(Me₂NCH₂)C₆H₄‐substituierter Oligosilane

ChemInform Abstract: Electronic and Electrochemical Properties of Platinum(II) and Platinum‐mercurycarboxylato Complexes Containing 2‐Me₂NCH₂C₅H₄‐, 2,6‐(Me₂NCH₂)₂C₆H₃‐ and 2‐Me₂NC₆H₄CH, Ligands.

Isomers of a Dibismuthane, R₂Bi−BiR₂ [R = 2,6-(Me₂NCH₂)₂C₆H₃], and Unusual Reactions with Oxygen: Formation of [R₂Bi]₂(O₂) and R‘R‘ ‘Bi [R‘ = 2-(Me₂NCH₂)-6-{Me₂N(O)CH₂}C₆H₃; R‘ ‘ = 2-(Me₂NCH₂)-6-{O(O)C}C₆H₃]

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Structures of 2‐(Me2NCH2)C6H4‐Substituted Oligosilanes

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ChemInform Abstract: Electronic and Electrochemical Properties of Platinum(II) and Platinum‐mercurycarboxylato Complexes Containing 2‐Me2NCH2C5H4‐, 2,6‐(Me2NCH2)2C6H3‐ and 2‐Me2NC6H4CH, Ligands.

Isomers of a Dibismuthane, R2Bi−BiR2 [R = 2,6-(Me2NCH2)2C6H3], and Unusual Reactions with Oxygen: Formation of [R2Bi]2(O2) and R‘R‘ ‘Bi [R‘ = 2-(Me2NCH2)-6-{Me2N(O)CH2}C6H3; R‘ ‘ = 2-(Me2NCH2)-6-{O(O)C}C6H3]

Activation of C−F and C−H Bonds by Platinum in Trifluorinated [C,N,N‘] Ligands. Crystal Structures of [PtFMe2{Me2NCH2CH2NHCH(CH2COMe)(2,4-C6H2F2)}] and [PtMe{Me2NCH2CH2NCH(2,3,4-C6HF3)}]

Hypercoordinated Organotin(IV) Halides Containing 2‐(Me2NCH2)C6H4 Groups: {2‐(Me2NCH2)C6H4}2SnX2 (X = F, Cl, Br, I) and {2‐(Me2NCH2)C6H4}R2SnX (R = Me, Ph; X = F, Cl, Br, I) and Their Solution Behaviour and Solid‐State, Hydrogen‐Bonding‐Based Supramolecular Architecture

Structures of 2‐(Me₂NCH₂)C₆H₄‐Substituted Oligosilanes

Strukturen 2‐(Me₂NCH₂)C₆H₄‐substituierter Oligosilane

ChemInform Abstract: Electronic and Electrochemical Properties of Platinum(II) and Platinum‐mercurycarboxylato Complexes Containing 2‐Me₂NCH₂C₅H₄‐, 2,6‐(Me₂NCH₂)₂C₆H₃‐ and 2‐Me₂NC₆H₄CH, Ligands.

Isomers of a Dibismuthane, R₂Bi−BiR₂ [R = 2,6-(Me₂NCH₂)₂C₆H₃], and Unusual Reactions with Oxygen: Formation of [R₂Bi]₂(O₂) and R‘R‘ ‘Bi [R‘ = 2-(Me₂NCH₂)-6-{Me₂N(O)CH₂}C₆H₃; R‘ ‘ = 2-(Me₂NCH₂)-6-{O(O)C}C₆H₃]

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