Clusters [{Pt(diphosphine)(isocyanide)}2Pt]2+ Recharacterized as [{Pt(diphosphine)(isocyanide)}2Hg]2+

Tomoaki Tanase; Yasuhiro Yamamoto; Richard J. Puddephatt

doi:10.1021/om9509498

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Clusters [{Pt(diphosphine)(isocyanide)}₂Pt]²⁺ Recharacterized as [{Pt(diphosphine)(isocyanide)}₂Hg]²⁺

Tomoaki Tanase Yasuhiro Yamamoto Richard J. Puddephatt

Year: 1996 Journal: Organometallics Vol: 15 (5)Pages: 1502-1504 Publisher: American Chemical Society

DOI: 10.1021/om9509498

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Abstract

The clusters already reported as [{Pt(diphos)(RNC)}2Pt](PF6)2, (diphos = cis-Ph2PCHCHPPh2, Ph2P(CH2)3PPh2, or tBu2P(CH2)2PtBu2; R = 2,6-xylyl or 2,4,6-mesityl) have been recharacterized to be the Pt−Hg−Pt mixed-metal clusters [{Pt(diphos)(RNC)}2Hg](PF6)2 on the basis of metal analysis and the re-evaluation of 31P{1H} NMR spectra and X-ray crystallographic structures.

Keywords:

Isocyanide Chemistry Metal NMR spectra database Crystallography Platinum Spectral line Stereochemistry Catalysis Physics Organic chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Inorganic Chemistry and Materials

Physical Sciences → Chemistry → Inorganic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Clusters [{Pt(diphosphine)(isocyanide)}₂Pt]²⁺ Recharacterized as [{Pt(diphosphine)(isocyanide)}₂Hg]²⁺

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Clusters [{Pt(diphosphine)(isocyanide)}2Pt]2+ Recharacterized as [{Pt(diphosphine)(isocyanide)}2Hg]2+

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