[Pt@Pb<sub>12</sub>]<sup>2−</sup>

Emren Nalbant Esentürk; James C. Fettinger; Yiu‐Fai Lam; Bryan W. Eichhorn

doi:10.1002/anie.200353287

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JOURNAL ARTICLE

[Pt@Pb₁₂]²⁻

Emren Nalbant Esentürk James C. Fettinger Yiu‐Fai Lam Bryan W. Eichhorn

Year: 2004 Journal: Angewandte Chemie International Edition Vol: 43 (16)Pages: 2132-2134 Publisher: Wiley

DOI: 10.1002/anie.200353287

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Abstract

It's platonic: The Pt centered [Pb12]2− icosahedron (depicted) was prepared from the [Pb9]4− Zintl ion and [Pt(PPh3)4] in good yield. The anion has virtual Ih point symmetry and is a rare example of a free-standing carbon-free aromatic inorganic cluster.

Keywords:

Yield (engineering) Ion Cluster (spacecraft) Crystallography Chemistry Carbon fibers Materials science

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Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Fullerene Chemistry and Applications

Physical Sciences → Chemistry → Organic Chemistry

Inorganic Chemistry and Materials

Physical Sciences → Chemistry → Inorganic Chemistry

[Pt@Pb₁₂]²⁻

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