JOURNAL ARTICLE

Struktur von bis(tetramethylethylcyclopentadienyl)zirkondichlorid, Cp2 oZrCl2 (Cp o = η 5-C5Me4Et)

Year: 1993 Journal:   Zeitschrift für Kristallographie - Crystalline Materials Vol: 205 (1)Pages: 61-67   Publisher: De Gruyter

Abstract

Abstract Cp o 2 ZrCl 2 ( Cp o = η 5 -C 5 Me 4 Et) crystallizes in the monoclinic space group P 2 1 / n (No. 14) ( T = 298 K) with a = 8.477(4), b = 18.280(7), c = 14.372(7) Å, β = 92.88(7)°, V = 2224.3 Å 3 and Z = 4. The refinement gives final R values R = 0.039 and R w = 0.039 for 3860 observed symmetry-independent reflections. The Zr atom is tetrahedrally coordinated by two Cp o ligands and two chloro ligands. The Cp o ligands adopt a staggered conformation.

Keywords:
Crystallography Monoclinic crystal system Crystal structure Chemistry Stereochemistry Physics

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Topics

Organometallic Complex Synthesis and Catalysis
Physical Sciences →  Chemistry →  Organic Chemistry
Organometallic Compounds Synthesis and Characterization
Physical Sciences →  Chemistry →  Organic Chemistry
Metal complexes synthesis and properties
Health Sciences →  Medicine →  Oncology

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JOURNAL ARTICLE

Struktur von bis(tetramethylethylcyclopentadienyl)- zirkondichlorid, Cp0 2ZrCl2 (Cp05-C5Me4Et)

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Journal:   Zeitschrift für Kristallographie - Crystalline Materials Year: 1993 Vol: 205 (1-2)Pages: 61-84
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