Bis(triphenylsilyl)phenylarsenite, PhAs(OSiPh<sub>3</sub>)<sub>2</sub>

George Ferguson; Brian O’Leary; Trevor R. Spalding

doi:10.1107/s1600536803028447

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Bis(triphenylsilyl)phenylarsenite, PhAs(OSiPh₃)₂

George Ferguson Brian O’Leary Trevor R. Spalding

Year: 2003 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 60 (1)Pages: m118-m120 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536803028447

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Abstract

The geometry at the As atom in the title compound, [As(C6H5)(C18H15OSi)2], is trigonal pyramidal, with C—As—O angles of 94.9 (2) and 99.9 (2)°, an O—As—O angle of 95.12 (19)°, As—O distances of 1.759 (4) and 1.786 (4) Å, and an As—C distance of 1.932 (5) Å. Four of the six independent phenyl rings in the two SiPh3 groups are disordered.

Keywords:

Crystallography Trigonal crystal system Atom (system on chip) Chemistry Geometry Physics Materials science Mathematics Crystal structure

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Organometallic Compounds Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Bis(triphenylsilyl)phenylarsenite, PhAs(OSiPh₃)₂

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