Efficient Catalysis of Ammonia Borane Dehydrogenation

M.C. Denney; Vincent Pons; Travis J. Hebden; D. Michael Heinekey; Karen I. Goldberg

doi:10.1021/ja062419g

ScienceGate Book Chapters

JOURNAL ARTICLE

Efficient Catalysis of Ammonia Borane Dehydrogenation

M.C. Denney Vincent Pons Travis J. Hebden D. Michael Heinekey Karen I. Goldberg

Year: 2006 Journal: Journal of the American Chemical Society Vol: 128 (37)Pages: 12048-12049 Publisher: American Chemical Society

DOI: 10.1021/ja062419g

Get Full-Text PDF Get Analytical Report

Abstract

In the presence of an iridium pincer complex, dehydrogenation of ammonia borane (H3NBH3) occurs rapidly at room temperature in tetrahydrofuran to generate 1.0 equivalent of H2 and [NH2BH2]5. A metal borohydride complex has been isolated as a dormant form of the catalyst which can be reactivated by reaction with H2.

Keywords:

Dehydrogenation Chemistry Ammonia borane Catalysis Pincer movement Borohydride Ammonia Iridium Tetrahydrofuran Borane Organic chemistry Inorganic chemistry Photochemistry

Metrics

620

Cited By

26.56

FWCI (Field Weighted Citation Impact)

Refs

1.00

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Hydrogen Storage and Materials

Physical Sciences → Materials Science → Materials Chemistry

Boron Compounds in Chemistry

Health Sciences → Medicine → Radiology, Nuclear Medicine and Imaging

Boron and Carbon Nanomaterials Research

Physical Sciences → Materials Science → Materials Chemistry

Efficient Catalysis of Ammonia Borane Dehydrogenation

Abstract

Metrics

Citation History

Topics

Related Documents

Efficient Catalysis of Ammonia Borane Dehydrogenation

ChemInform Abstract: Efficient Catalysis of Ammonia Borane Dehydrogenation

Efficient Organocatalytic Dehydrogenation of Ammonia Borane

Efficient Organocatalytic Dehydrogenation of Ammonia Borane

Ruthenium catalysis for ammonia borane dehydrogenation and dehydrative coupling