Synthese, Struktur und Reaktivität von [Mn2(μ‐H)2(CO)6(μ‐Ph2PCH2PPh2)]

Francisco J. Garcı́a Alonso; Manuel García Sanz; Vı́ctor Riera; Miguel A. Ruiz; António Tiripicchio; Marisa Tiripicchio Camellini

doi:10.1002/ange.19881000923

JOURNAL ARTICLE

Synthese, Struktur und Reaktivität von [Mn₂(μ‐H)₂(CO)₆(μ‐Ph₂PCH₂PPh₂)]

Francisco J. Garcı́a Alonso Manuel García Sanz Vı́ctor Riera Miguel A. Ruiz António Tiripicchio Marisa Tiripicchio Camellini

Year: 1988 Journal: Angewandte Chemie Vol: 100 (9)Pages: 1224-1225 Publisher: Wiley

DOI: 10.1002/ange.19881000923

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Abstract

Intra‐ und intermolekulare H 2 ‐Eliminierung sowie Insertion in eine Mn 2 (μ‐H)‐Brücke , das sind die Reaktionsmöglichkeiten der Titelverbindung 1 . Ihre hohe Reaktivität zeigt sich bei Umsetzungen mit MeC 6 H 4 SH, S 8 , t BuNC, MeCN und Alkinen. Der Mn‐Mn‐Abstand in 1 beträgt 2.699(2) Å. magnified image

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Chemistry Stereochemistry Medicinal chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Metal-Catalyzed Oxygenation Mechanisms

Physical Sciences → Chemistry → Inorganic Chemistry

Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Synthese, Struktur und Reaktivität von [Mn₂(μ‐H)₂(CO)₆(μ‐Ph₂PCH₂PPh₂)]

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