Synthesis, Structure, and Reactivity of [Mn2(μ‐H)2(CO)6(μ‐Ph2PCH2PPh2)]

Francisco J. Garcı́a Alonso; Manuel García Sanz; Vı́ctor Riera; Miguel A. Ruiz; António Tiripicchio; Marisa Tiripicchio Camellini

doi:10.1002/anie.198811671

JOURNAL ARTICLE

Synthesis, Structure, and Reactivity of [Mn₂(μ‐H)₂(CO)₆(μ‐Ph₂PCH₂PPh₂)]

Francisco J. Garcı́a Alonso Manuel García Sanz Vı́ctor Riera Miguel A. Ruiz António Tiripicchio Marisa Tiripicchio Camellini

Year: 1988 Journal: Angewandte Chemie International Edition in English Vol: 27 (9)Pages: 1167-1168

DOI: 10.1002/anie.198811671

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Abstract

The title compound 1 is capable of undergoing intra- and intermolecular H2-elimination reactions as well as insertion into a Mn2(μ-H) bridge. Its high reactivity is revealed in reactions with p-MeC6H4SH, S8, tBuNC, MeCN and alkynes. The Mn-Mn distance in 1 is 2.699(2) Å.

Keywords:

Reactivity (psychology) Intermolecular force Chemistry Manganese Crystallography Molecule Organic chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Fluorine in Organic Chemistry

Life Sciences → Pharmacology, Toxicology and Pharmaceutics → Pharmaceutical Science

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Synthesis, Structure, and Reactivity of [Mn₂(μ‐H)₂(CO)₆(μ‐Ph₂PCH₂PPh₂)]

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