Assignment of Electronic Spectra of the Platinum(III) Dimer Complexes [Pt2(SO4)4(H2O)2]2- and [Pt2(HPO4)4(H2O)2]2-

Robert Stranger; Sandra C. Nissen; Michael Mathieson; Trevor G. Appleton

doi:10.1021/ic951614l

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Assignment of Electronic Spectra of the Platinum(III) Dimer Complexes [Pt₂(SO₄)₄(H₂O)₂]²^- and [Pt₂(HPO₄)₄(H₂O)₂]²^-

Robert Stranger Sandra C. Nissen Michael Mathieson Trevor G. Appleton

Year: 1997 Journal: Inorganic Chemistry Vol: 36 (5)Pages: 937-939 Publisher: American Chemical Society

DOI: 10.1021/ic951614l

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Abstract

The electronic spectra of the tetrabridged platinum(III) lantern dimers [Pt2(SO4)4(H2O)2]2- and [Pt2(HPO4)4(H2O)2]2- are re-examined in light of recent electronic structure calculations and spectral assignments for the analogous acetate-bridged complex [Pt2(O2CCH3)4(H2O)2]2+.

Keywords:

Chemistry Platinum Dimer Spectral line Electronic structure Crystallography Inorganic compound Stereochemistry Computational chemistry Catalysis

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Assignment of Electronic Spectra of the Platinum(III) Dimer Complexes [Pt₂(SO₄)₄(H₂O)₂]²^- and [Pt₂(HPO₄)₄(H₂O)₂]²^-

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