JOURNAL ARTICLE
Darstellung und Eigenschaften von CH3C(CH2PPh2)3MoCl3 / Characterization and Properties of CH3C(CH2PPh2)3MoCl3
Olaf WalterGottfried HüttnerLászló Zsolnai
Year: 1993 Journal: Zeitschrift für Naturforschung B Vol: 48 (5)Pages: 636-640 Publisher: De Gruyter
Abstract
Starting from MoCl 5 via the intermediates (MeCN) 2 MoCl4 (1) and (THF) 2 MoCl 4 (2) the tripod complex CH 3 C(CH 2 PPh 2 ) 3 MoCl 3 (4) has been synthesized. The yellow cristalline compound 4 has been fully characterized by standard analytical techniques. X-ray-analysis proves the facial coordination of the tripod ligand. To our knowledge 4 is the first Mo(III)-trihalide coordination compound containing three P-donor-ligands in a facial coordination.
Keywords:
Chemistry Tripod (photography) Trihalide Ligand (biochemistry) Crystallography Coordination complex Stereochemistry Metal Inorganic chemistry Physics Organic chemistry Halide
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Topics
Organometallic Complex Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
Synthesis and characterization of novel inorganic/organometallic compounds
Physical Sciences → Chemistry → Inorganic Chemistry
Chemical Synthesis and Analysis
Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology
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