Thermal reaction of (CH3)2C=C(CH3)2 in the presence of di-tert-butyl peroxide; reactions of the radicals ˙CH3, (CH3)3C˙C(CH3)2 and (CH3)2C=C(CH3)˙CH2

Tamás Körtvélyesi; Lászloó Seres

doi:10.1051/jcp/1996930253

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Thermal reaction of (CH₃)₂C=C(CH₃)₂ in the presence of di-tert-butyl peroxide; reactions of the radicals ˙CH₃, (CH₃)₃C˙C(CH₃)₂ and (CH₃)₂C=C(CH₃)˙CH₂

Tamás Körtvélyesi Lászloó Seres

Year: 1996 Journal: Journal de Chimie Physique Vol: 93 Pages: 253-273 Publisher: EDP Sciences

DOI: 10.1051/jcp/1996930253

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Abstract

A study of the thermal reaction of (CH3)2C=C(CH3)2 (23DMB2) in the presence of di-t-butyl peroxide (PODBT) at 389-451 K yielded kinetic data on some reactions of the radicals ˙CH3, (CH3)3C˙C(CH3)2 (1122TMP˙) and (CH3)2C=C(CH3)˙CH2 (112TMA˙).

Keywords:

Radical Peroxide Chemistry Organic peroxide Kinetic energy Medicinal chemistry Organic chemistry Polymer

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Thermal reaction of (CH₃)₂C=C(CH₃)₂ in the presence of di-tert-butyl peroxide; reactions of the radicals ˙CH₃, (CH₃)₃C˙C(CH₃)₂ and (CH₃)₂C=C(CH₃)˙CH₂

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