JOURNAL ARTICLE
The red form of [Re(phen)(CO)3(H2O)]CF3SO3.H2O
William B. ConnickAngel J. Di BilioW. P. SchaefferHarry B. Gray
Year: 1999 Journal: Acta Crystallographica Section C Crystal Structure Communications Vol: 55 (6)Pages: 913-916 Publisher: Wiley
Abstract
The coordination geometry of the cations in the red form of aquatricarbonyl(1,10-phenanthroline-N,N')rhenium(I) trifluoromethanesulfonate hydrate, [Re(C12H8N2)(CO)3-(H2O)]CF3SO3.H2O, is approximately octahedral, with a facial arrangement of the linearly coordinated carbonyl ligands. The phenanthroline (phen) ligands interleave to form a columnar pi-stacked structure.
Keywords:
Rhenium Trifluoromethanesulfonate Hydrate Octahedron Phenanthroline Crystallography Chemistry Inorganic chemistry Stereochemistry Crystal structure Catalysis
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Topics
Chemical Synthesis and Analysis
Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology
Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences → Chemistry → Inorganic Chemistry
Metal complexes synthesis and properties
Health Sciences → Medicine → Oncology
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