Beyond Wingtips: Backbone Alkylation Affects the Orientation of N-Heterocyclic Carbenes on Gold Nanoparticles

Ahmadreza Nezamzadeh; Shayanta Chowdhury; Gaohe Hu; Nathaniel L. Dominique; Emmett ED Desroche; Sakiat SH Hossain; Mark D. Aloisio; Michael MF Furlan; Ryan R. K. RRKG Groome; Kayla KB Boire; A. B. McLean; Lasse Jensen; Jon Camden; Cathleen M. Crudden

doi:10.1039/d5sc05986k

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Beyond Wingtips: Backbone Alkylation Affects the Orientation of N-Heterocyclic Carbenes on Gold Nanoparticles

Ahmadreza Nezamzadeh Shayanta Chowdhury Gaohe Hu Nathaniel L. Dominique Emmett ED Desroche Sakiat SH Hossain Mark D. Aloisio Michael MF Furlan Ryan R. K. RRKG Groome Kayla KB Boire A. B. McLean Lasse Jensen Jon Camden Cathleen M. Crudden

Year: 2026 Journal: Chemical Science Publisher: Royal Society of Chemistry

DOI: 10.1039/d5sc05986k

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Abstract

ABSTRACT: The effect of wingtip groups on the orientation of N-heterocyclic carbene (NHC)–based self-assembled monolayers (SAMs) on a variety of metal surfaces has received considerable attention. However, the influence of...

Keywords:

Carbene Orientation (vector space) Monolayer Metal Alkylation Colloidal gold

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Topics

N-Heterocyclic Carbenes in Organic and Inorganic Chemistry

Physical Sciences → Chemistry → Organic Chemistry

Molecular Junctions and Nanostructures

Physical Sciences → Engineering → Electrical and Electronic Engineering

Synthesis and Properties of Aromatic Compounds

Physical Sciences → Chemistry → Organic Chemistry

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