Photocatalytic Study of Cyanide Oxidation Using Titanium Dioxide (TiO2)-Activated Carbon Composites in a Continuous Flow Photo-Reactor

Abstract

The photocatalytic oxidation of cyanide by titanium dioxide (TiO2) supported on activated carbon (AC) was evaluated in a continuous flow UV photo-reactor. The continuous photo-reactor was made of glass and covered with a wood box to isolate the fluid of external conditions. The TiO2-AC synthesized by the impregnation of TiO2 on granular AC composites was characterized by inductively coupled plasma optical emission spectrometry (ICP-OES), Scanning Electron Microscopy (SEM), and nitrogen adsorption-desorption isotherms. Photocatalytic and adsorption tests were conducted separately and simultaneously. The results showed that 97% of CN− was degraded within 24 h due to combined photocatalytic oxidation and adsorption. To estimate the contribution of only adsorption, two-stage tests were performed. First, 74% cyanide ion degradation was reached in 24 h under dark conditions. This result was attributed to CN− adsorption and oxidation due to the generation of H2O2 on the surface of AC. Then, 99% degradation of cyanide ion was obtained through photocatalysis during 24 h. These results showed that photocatalysis and the continuous photo-reactor's design enhanced the photocatalytic cyanide oxidation performance compared to an agitated batch system. Therefore, the use of TiO2-AC composites in a continuous flow photo-reactor is a promising process for the photocatalytic degradation of cyanide in aqueous solutions.