JOURNAL ARTICLE

High Dielectric Fe<sub>3</sub>O<sub>4</sub> and Fe<sub>2</sub>O<sub>3</sub> Nanoparticles Deposited on Graphite Nanosheets\nfor Electromagnetic Wave Absorption

Abstract

Fe<sub>3</sub>O<sub>4</sub>/graphite nanosheets (GNs) nanocomposites\nwere obtained by the solvothermal method and calcined in an air environment\nto obtain Fe<sub>2</sub>O<sub>3</sub>/GNs nanocomposites. The phase\nand microstructure can clearly demonstrate the evolution process of\nFe<sub>3</sub>O<sub>4</sub>/GNs to Fe<sub>2</sub>O<sub>3</sub>/GNs\nnanocomposites. The Fe<sub>3</sub>O<sub>4</sub>/GNs nanocomposites\nwill be converted from Fe<sub>3</sub>O<sub>4</sub> to Fe<sub>2</sub>O<sub>3</sub> during calcination to form nanoparticles. When the\ncalcination temperature is 250 °C, the glucose on the surface\nof the S-250 sample begins to carbonize, resulting in an excellent\nreflection loss value of −66.593 dB when the thickness is 2.8\nmm and the effective absorption bandwidth is 3.28 GHz. The mutual\ncontact between the nanoparticles and GNs makes the composites produce\nmore interface/dipole polarization and better impedance matching.\nCalcination converts Fe<sub>3</sub>O<sub>4</sub>/GNs to Fe<sub>2</sub>O<sub>3</sub>/GNs, which is a high-performance design with a unique\nstructure and has potential applications in the field of electromagnetic-wave\nabsorption.

Keywords:
Calcination Microstructure Nanoparticle Graphite Dielectric Dielectric loss Absorption (acoustics) Polarization (electrochemistry)

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