Two Novel Thioindate-Thioantimonate Compounds [Ni(dien)<sub>2</sub>]<sub>2</sub>In<sub>2</sub>Sb<sub>4</sub>S<sub>11</sub> and [Ni(dien)<sub>2</sub>]<sub>3</sub>(In<sub>3</sub>Sb<sub>2</sub>S<sub>9</sub>)<sub>2</sub>·2H<sub>2</sub>O with Transition Metal Complexes
Jian Zhou (28020)Xian-Hong Yin (577605)Feng Zhang (6548)
Abstract
Two novel thioindate-thioantimonate compounds [Ni(dien)<sub>2</sub>]<sub>2</sub>In<sub>2</sub>Sb<sub>4</sub>S<sub>11</sub> (<b>1</b>) and [Ni(dien)<sub>2</sub>]<sub>3</sub>(In<sub>3</sub>Sb<sub>2</sub>S<sub>9</sub>)<sub>2</sub>·2H<sub>2</sub>O (<b>2</b>) (dien = diethylenetriamine) have been solvothermally synthesized and structurally characterized. <b>1</b> contains heterometallic pseudosemicube [In<sub>2</sub>SbS<sub>8</sub>] clusters and bow-like trimeric [Sb<sub>3</sub>S<sub>7</sub>] units, which are linked to form a [In<sub>2</sub>Sb<sub>4</sub>S<sub>11</sub><sup>4−</sup>]<sub><i>n</i></sub> chain, whereas <b>2</b> consists of chain-like [In<sub>6</sub>S<sub>18</sub>] units and pyramidal SbS<sub>3</sub>, which are interconnected to give a [In<sub>3</sub>Sb<sub>2</sub>S<sub>9</sub><sup>6−</sup>]<sub><i>n</i></sub> layer with a large rectangle-like 12-ring. The optical properties of <b>1</b> and <b>2</b> have been investigated by UV−vis spectroscopy.
Metrics
Topics
Related Documents
New Vanadium Selenites:\nCentrosymmetric Ca<sub>2</sub>(VO<sub>2</sub>)<sub>2</sub>(SeO<sub>3</sub>)<sub>3</sub>(H<sub>2</sub>O)<sub>2</sub>, Sr<sub>2</sub>(VO<sub>2</sub>)<sub>2</sub>(SeO<sub>3</sub>)<sub>3</sub>, and Ba(V<sub>2</sub>O<sub>5</sub>)(SeO<sub>3</sub>), and Noncentrosymmetric and Polar\nA<sub>4</sub>(VO<sub>2</sub>)<sub>2</sub>(SeO<sub>3</sub>)<sub>4</sub>(Se<sub>2</sub>O<sub>5</sub>) (A = Sr<sup>2+</sup> or Pb<sup>2+</sup>)
Jeongho Yeon (1406326)Sang-Hwan Kim (527119)Sau Doan Nguyen (1985821)Hana Lee (445860)P. Shiv Halasyamani (1261704)
Synthesis, Structure and Photocatalytic Property of [Ni(en)<sub>2</sub>]{[Ni(en)<sub>2</sub>]<sub>2</sub>[Mo<sub>8</sub>V<sub>8</sub>O<sub>40</sub>(VO<sub>4</sub>)]}[(NH<sub>2</sub>)<sub>2</sub>(C<sub>2</sub>H<sub>4</sub>)<sub>2</sub>NH]<sub>2</sub>·2H<sub>2</sub>O
Expanding the Remarkable Structural Diversity of Uranyl Tellurites: \nHydrothermal Preparation and Structures of K[UO<sub>2</sub>Te<sub>2</sub>O<sub>5</sub>(OH)],\nTl<sub>3</sub>{(UO<sub>2</sub>)<sub>2</sub>[Te<sub>2</sub>O<sub>5</sub>(OH)](Te<sub>2</sub>O<sub>6</sub>)}·2H<sub>2</sub>O, β-Tl<sub>2</sub>[UO<sub>2</sub>(TeO<sub>3</sub>)<sub>2</sub>], and\nSr<sub>3</sub>[UO<sub>2</sub>(TeO<sub>3</sub>)<sub>2</sub>](TeO<sub>3</sub>)<sub>2</sub>
Philip M. Almond (2509114)Thomas E. Albrecht-Schmitt (1370601)
Influence of Hydrogen Bonding on the Assembly of Six-Membered Vanadium\nBorophosphate Cluster Anions: Synthesis and Structures of\n(NH<sub>4</sub>)<sub>2</sub>(C<sub>2</sub>H<sub>10</sub>N<sub>2</sub>)<sub>6</sub>[Sr(H<sub>2</sub>O)<sub>5</sub>]<sub>2</sub>[V<sub>2</sub>P<sub>2</sub>BO<sub>12</sub>]<sub>6</sub>·10H<sub>2</sub>O,\n(NH<sub>4</sub>)<sub>2</sub>(C<sub>3</sub>H<sub>12</sub>N<sub>2</sub>)<sub>6</sub>[Sr(H<sub>2</sub>O)<sub>4</sub>]<sub>2</sub>[V<sub>2</sub>P<sub>2</sub>BO<sub>12</sub>]<sub>6</sub>·17H<sub>2</sub>O, and\n(NH<sub>4</sub>)<sub>3</sub>(C<sub>4</sub>H<sub>14</sub>N<sub>2</sub>)<sub>4.5</sub>[Sr(H<sub>2</sub>O)<sub>5</sub>]<sub>2</sub>[Sr(H<sub>2</sub>O)<sub>4</sub>][V<sub>2</sub>P<sub>2</sub>BO<sub>12</sub>]<sub>6</sub>·10H<sub>2</sub>O
Junghwan Do (2102317)Ranko P. Bontchev (2425492)Allan J. Jacobson (1644922)
Energy Partitioning Analysis of the Bonding in\nL<sub>2</sub>TM−C<sub>2</sub>H<sub>2</sub> and L<sub>2</sub>TM−C<sub>2</sub>H<sub>4</sub> (TM = Ni, Pd, Pt; L<sub>2</sub> =\n(PH<sub>3</sub>)<sub>2</sub>, (PMe<sub>3</sub>)<sub>2</sub>, H<sub>2</sub>PCH<sub>2</sub>PH<sub>2</sub>, H<sub>2</sub>P(CH<sub>2</sub>)<sub>2</sub>PH<sub>2</sub>)<sup>†</sup>
Chiara Massera (547887)Gernot Frenking (1569796)