Chromatography in a Single Metal−Organic Framework (MOF) Crystal

Shuangbing Han (1576345); Yanhu Wei (1576336); Cory Valente (2101246); István Lagzi (1270497); Jeremiah J. Gassensmith (2103007); Ali Coskun (1477723); J. Fraser Stoddart (547860); Bartosz A. Grzybowski (1270503)

JOURNAL ARTICLE

Chromatography in a Single Metal−Organic Framework (MOF) Crystal

Shuangbing Han (1576345)Yanhu Wei (1576336)Cory Valente (2101246)István Lagzi (1270497)Jeremiah J. Gassensmith (2103007)Ali Coskun (1477723)J. Fraser Stoddart (547860)Bartosz A. Grzybowski (1270503)

Year: 2016 Journal: OPAL (Open@LaTrobe) (La Trobe University) Publisher: La Trobe University

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Abstract

Millimeter-sized single MOF-5 crystals are used as “chromatographic columns” to effectively separate mixtures of organic dyes. Remarkably, owing to the nanoscopic pore dimensions and the molecular-level interactions between the migrating molecules and the MOF scaffold, the separations occur over a distance of only a few hundred micrometers which is unambiguously confirmed by fluorescence confocal microscopy.

Keywords:

Nanoscopic scale Crystal (programming language) Fluorescence Confocal Molecule Organic molecules

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Zeolite Catalysis and Synthesis

Physical Sciences → Chemistry → Inorganic Chemistry

X-ray Diffraction in Crystallography

Physical Sciences → Materials Science → Materials Chemistry

Chromatography in a Single Metal−Organic Framework (MOF) Crystal

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