[Tc<sup>I</sup>(CN)<sub>3</sub>(CO)<sub>3</sub>]<sup>2-</sup> and [Re<sup>I</sup>(CN)<sub>3</sub>(CO)<sub>3</sub>]<sup>2-</sup>: Case Studies for the Binding\nProperties of CN<sup>-</sup> and CO
Philipp Kurz (1498345)Bernhard Spingler (1507018)Thomas Fox (1320582)Roger Alberto (1417855)
Abstract
The cyano carbonyl complexes [<sup>99</sup>Tc(CN)<sub>3</sub>(CO)<sub>3</sub>]<sup>2-</sup> and [Re(CN)<sub>3</sub>(CO)<sub>3</sub>]<sup>2-</sup> were synthesized and fully characterized. These complexes are additional members of the well-known d<sup>6</sup> transition metal\ncomplex series [M(CN)<sub>3</sub>(CO)<sub>3</sub>]<i><sup>n</sup></i><sup>-</sup>. The analytical data obtained in\nthis study thus offer a unique opportunity to study similarities and\ndifferences of cyanide and carbonyl binding in transition metal\ncomplexes.
Metrics
Topics
Related Documents
Polyoxopalladates Encapsulating\n8‑Coordinated Metal Ions, [MO<sub>8</sub>Pd<sup>II</sup><sub>12</sub>L<sub>8</sub>]<sup><i>n</i>−</sup> (M =\nSc<sup>3+</sup>, Mn<sup>2+</sup>, Fe<sup>3+</sup>, Co<sup>2+</sup>, Ni<sup>2+</sup>, Cu<sup>2+</sup>, Zn<sup>2+</sup>, Lu<sup>3+</sup>; L = PhAsO<sub>3</sub><sup>2–</sup>, PhPO<sub>3</sub><sup>2–</sup>, SeO<sub>3</sub><sup>2–</sup>)
Maria Barsukova-Stuckart (2012446)Natalya V. Izarova (2012452)Ryan A. Barrett (2012449)Zhenxing Wang (201180)Johan van Tol (1262361)Harold W. Kroto (2012443)Naresh S. Dalal (1540159)Pablo Jiménez-Lozano (1851982)Jorge J. Carbó (1518559)Josep M. Poblet (1406476)Marc S. von Gernler (1348317)Thomas Drewello (1348314)Pedro de Oliveira (1573621)Bineta Keita (1483588)Ulrich Kortz (1290630)
Vielseitige Polysulfido-Liganden in den neuartigen Komplexen [Sn<sup>IV</sup>(S<sub>4</sub>)<sub>3</sub>]<sup>2⊖</sup>, [Sn<sup>IV</sup>(S<sub>4</sub>)<sub>2</sub>(S<sub>6</sub>)]<sup>2⊖</sup>, [Cr<sup>III</sup>(NH<sub>3</sub>)<sub>2</sub>(S<sub>5</sub>)<sub>2</sub>]<sup>⊖</sup>, [Ag<sup>I</sup>(S<sub>9</sub>)]<sup>⊖</sup> und [Nb<sup>V</sup><sub>2</sub>(OMe)<sub>2</sub>(S<sub>2</sub>)<sub>3</sub>(S<sub>5</sub>)O]<sup>2⊖</sup>
Achim MüllerJürgen SchimanskiMichael RömerHartmut BöggeFriedrich‐Wilhelm BaumannWerner EltznerErich KrickemeyerUlrich Billerbeck
[Tc<sup>I</sup>(NO)X(Cp)(PPh<sub>3</sub>)] Complexes\n(X<sup>–</sup> = I<sup>–</sup>, I<sub>3</sub><sup>–</sup>, SCN<sup>–</sup>, CF<sub>3</sub>SO<sub>3</sub><sup>–</sup>, or CF<sub>3</sub>COO<sup>–</sup>) and Their Reactions
Janine Ackermann (7816403)Abdullah Abdulkader (7816406)Clemens Scholtysik (6523736)Maximilian Roca Jungfer (7816409)Adelheid Hagenbach (1803811)Ulrich Abram (1584805)
2,4,6-Tris(2-pyridyl)-1,3,5-triazine (tptz)-Derived [Ru<sup>II</sup>(tptz)(acac)(CH<sub>3</sub>CN)]<sup>+</sup>\nand Mixed-Valent [(acac)<sub>2</sub>Ru<sup>III</sup>{(<i>μ</i>-tptz-H<sup>+</sup>)<sup>-</sup>}Ru<sup>II</sup>(acac)(CH<sub>3</sub>CN)]<sup>+</sup><sup>†</sup>
Sandeep Ghumaan (2647036)Sanjib Kar (1716496)Shaikh M. Mobin (1545712)B. Harish (2647039)Vedavati G. Puranik (562481)Goutam Kumar Lahiri (1415638)
PO<sub>2</sub><sup>3–</sup> and AsO<sup>3–</sup>: Pnictogenide\nLigands in the Highly Charged Re<sub>4</sub> Cluster\nAnions [{Re<sub>4</sub>(PO)<sub>3</sub>(PO<sub>2</sub>)}(CN)<sub>12</sub>]<sup>8–</sup>, [{Re<sub>4</sub>As<sub>2</sub>(AsO)<sub>2</sub>}(CN)<sub>12</sub>]<sup>8–</sup>, and [{Re<sub>4</sub>(AsO)<sub>4</sub>}(CN)<sub>12</sub>]<sup>8–</sup>
Aleksei S. Pronin (6706148)Anton I. Smolentsev (674373)Svetlana G. Kozlova (1491634)Igor N. Novozhilov (4454827)Yuri V. Mironov (674374)