Diastereoselective Electrophilic α‑Hydroxyamination\nof <i>N</i>-<i>tert</i>-Butanesulfinyl Imidates
Peng-Ju Ma (3640807)Hui Liu (33624)Chong-Dao Lu (1393924)Yan-Jun Xu (639271)
Abstract
Diastereoselective α-hydroxyamination\nof <i>N</i>-<i>tert</i>-butanesulfinyl imidates\nusing nitrosoarenes\nis reported. A catalytic amount of base effectively promotes the hydroxyamination\nreaction of α-aryl-substituted imidates, and the resulting α-hydroxyamino\nimidates can be transformed into a range of synthetically useful intermediates.
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