A Microporous Metal–Organic Framework for Efficient\nC<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> and C<sub>2</sub>H<sub>6</sub>/CH<sub>4</sub> Separation
Hengbo Li (1423666)Zhenyu Ji (6291644)Cheng Chen (136164)Zhengyi Di (4751727)Yongsheng Liu (142720)Mingyan Wu (1645222)
Abstract
Owing\nto the critical industrial value, the applications of MOFs\nin the field of light hydrocarbon gases storage and separation have\nattracted increasing attention. In this work, a microporous material,\nwhich is composed of typical dicopper paddlewheels and diisophthalate\nligands, has been successfully synthesized. It exhibits good gas separation\nability for C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> mixtures and\nC<sub>2</sub>H<sub>6</sub>/CH<sub>4</sub> mixtures, respectively.\nConfirmed by the breakthrough experiments, the separation time of\nC<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> mixtures (50/50) and C<sub>2</sub>H<sub>6</sub>/CH<sub>4</sub> mixtures (15/85) can reach up\nto 36 and 95 min/g, respectively (gas flow rate = 2 cm<sup>3</sup>/min).
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