JOURNAL ARTICLE

Assembly of Four Kinds of Cages into Porous Metal–Organic\nFramework for Selective Sorption of Light Hydrocarbons

Fei Wang (19534)Hong-Ru Fu (1625920)Duan-Chuan Hou (1711387)Jian Zhang (1682)

Year: 2016 Journal:   OPAL (Open@LaTrobe) (La Trobe University)   Publisher: La Trobe University

Abstract

The\ndirect assembly of four kinds of cages by face-sharing and\nedge-sharing modes with Zn<sub>3</sub>(μ<sub>3</sub>-OH<sup>–</sup>)­(H<sub>2</sub>O)­(COO<sup>–</sup>)<sub>4</sub> units and organic ligands generates a porous framework\nmaterial including 3D channels, which shows high adsorption enthalpy\nof C<sub>3</sub>H<sub>8</sub> (35 kJ/mol) and excellent adsorption\nselectivity of C<sub>3</sub>H<sub>8</sub> over CH<sub>4</sub> under\nambient conditions.

Keywords:
Sorption Adsorption Porosity Porous medium Hydrocarbon Metal-organic framework Absorption (acoustics) Polymer

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Topics

Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences →  Chemistry →  Inorganic Chemistry
Mesoporous Materials and Catalysis
Physical Sciences →  Materials Science →  Materials Chemistry
Covalent Organic Framework Applications
Physical Sciences →  Materials Science →  Materials Chemistry
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