Metastable Interwoven Mesoporous Metal–Organic\nFrameworks
Yabing He (1812187)Zhiyong Guo (110695)Shengchang Xiang (1431784)Zhangjing Zhang (1431781)Wei Zhou (24328)FrankR. Fronczek (1371459)Sean Parkin (1742122)Stephen T. Hyde (1658779)Michael O’Keeffe (1414261)Banglin Chen (1525054)
Abstract
Three isostructural interwoven 3,4-connected\nmesoporous metal–organic frameworks of pto-a topology (<b>UTSA-28-Cu</b>, <b>UTSA-28-Zn</b>, and <b>UTSA-28-Mn</b>) were synthesized and structurally characterized. Because of their\nmetastable nature, their gas sorption properties are highly dependent\non the metal ions and activation profiles. The most stable, <b>UTSA-28a-Cu</b>, exhibits promising gas storage and separation\ncapacities.
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