Defect-Engineered Chiral Metal–Organic Frameworks\nfor Efficient Asymmetric Aldol Reaction

Zijuan Chen (5469707); Xiaodan Yan (363435); Meiyan Li (441468); Shuhua Wang (1305378); Chao Chen (195669)

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Defect-Engineered Chiral Metal–Organic Frameworks\nfor Efficient Asymmetric Aldol Reaction

Zijuan Chen (5469707)Xiaodan Yan (363435)Meiyan Li (441468)Shuhua Wang (1305378)Chao Chen (195669)

Year: 2021 Journal: OPAL (Open@LaTrobe) (La Trobe University) Publisher: La Trobe University

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Abstract

By\nemployment of a mixed truncated chiral ligand synthetic strategy,\na defect-engineered chiral metal–organic framework with hierarchical\nmicro/mesoporous structure was prepared, and it exhibited efficient\nheterogeneous catalytic activity and enantioselectivity for asymmetric\naldol reaction.

Keywords:

Catalysis Ligand (biochemistry) Enantioselective synthesis Chiral ligand Yield (engineering) Chirality (physics)

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Covalent Organic Framework Applications

Physical Sciences → Materials Science → Materials Chemistry

Supramolecular Chemistry and Complexes

Physical Sciences → Chemistry → Organic Chemistry

Defect-Engineered Chiral Metal–Organic Frameworks\nfor Efficient Asymmetric Aldol Reaction

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