Synthesis and Reactivity of the Carbaalanes\n(AlH)&lt;sub&gt;6&lt;/sub&gt;(AlNMe&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;(CCH&lt;sub&gt;2&lt;/sub&gt;C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;FeC&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;6&lt;/sub&gt; and\n(AlH)&lt;sub&gt;6&lt;/sub&gt;(AlNMe&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;(CCH&lt;sub&gt;2&lt;/sub&gt;Ph)&lt;sub&gt;6&lt;/sub&gt;:  X-ray Crystal Structure of\n(AlH)&lt;sub&gt;6&lt;/sub&gt;(AlNMe&lt;sub&gt;3&lt;/sub&gt;)&lt;sub&gt;2&lt;/sub&gt;(CCH&lt;sub&gt;2&lt;/sub&gt;C&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;4&lt;/sub&gt;FeC&lt;sub&gt;5&lt;/sub&gt;H&lt;sub&gt;5&lt;/sub&gt;)&lt;sub&gt;6&lt;/sub&gt;&lt;sup&gt;†&lt;/sup&gt;

S. Shravan Kumar (2660209); Junfeng Rong (1414717); Sanjay Singh (69314); Herbert W. Roesky (560521); Denis Vidovic (2710594); Jörg Magull (2431678); Dante Neculai (2713636); Vadapalli Chandrasekhar (815391); Marc Baldus (271753)

JOURNAL ARTICLE

Synthesis and Reactivity of the Carbaalanes\n(AlH)6(AlNMe3)2(CCH2C5H4FeC5H5)6 and\n(AlH)6(AlNMe3)2(CCH2Ph)6: X-ray Crystal Structure of\n(AlH)6(AlNMe3)2(CCH2C5H4FeC5H5)6†

S. Shravan Kumar (2660209)Junfeng Rong (1414717)Sanjay Singh (69314)Herbert W. Roesky (560521)Denis Vidovic (2710594)Jörg Magull (2431678)Dante Neculai (2713636)Vadapalli Chandrasekhar (815391)Marc Baldus (271753)

Year: 2016 Journal: OPAL (Open@LaTrobe) (La Trobe University) Publisher: La Trobe University

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Abstract

The synthesis of the aluminum carbide clusters (AlH)6(AlNMe3)2(CCH2C5H4FeC5H5)6 (1),\ncontaining an assembly of ferrocenylmethylene substituents, and (AlH)6(AlNMe3)2(CCH2Ph)6 (2) was carried out by the hydroalumination of FcC⋮CH (Fc = ferrocenyl) and (PhC⋮C)3Al·NMe3, respectively, with AlH3·NMe3. Compound 1 is made up of an Al−C framework\nwith eight aluminum atoms occupying the corners of a rhombic cube while the six carbon\natoms cap the faces of the cube. The reaction of (AlH)6(AlNMe3)2(CCH2Ph)6 (2) with FcC⋮CH and PhC⋮CH leads to the formation of (AlH)2(FcC⋮CAl)4(AlNMe3)2(CCH2Ph)6 (3) and\n(PhC⋮C)3Al·NMe3 (4), respectively. Reaction of 4 with AlH3·NMe3 results in the formation\nof 2.

Keywords:

Nucleofection Gestational period TSG101 Liquation Diafiltration Dysgeusia Fusible alloy Emperipolesis Hemopericardium

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Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

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